|
|
geranyl_diphosphate <=> (-)-limonene + diphosphate
|
4.2.3.101
7-epi-sesquithujene synthase
4.2.3.102
sesquithujene synthase
4.2.3.118
2-methylisoborneol synthase
4.2.3.16
(4S)-limonene synthase
|
–
–
–
–
|
MK
|
|
BRENDA:
BR22831;
BS398891
KEGG:
R02013
MetaCyc:
4.2.3.16-RXN
|
|
|
|
(-)-limonene + H2O + acceptor <=> (S)-perillyl_alcohol + reduced_acceptor
|
1.17.99.8
limonene dehydrogenase
|
–
|
M
|
|
BRENDA:
BR53026
KEGG:
R12591
MetaCyc:
RXN-20138;
RXN-20143
|
|
|
|
(-)-limonene + O2 + NADPH + H+ <=> (-)-cis-carveol + H2O + NADP+
|
1.14.13
1.14.14.53
(R)-limonene 6-monooxygenase
|
–
–
|
|
|
BRENDA:
BS355939
MetaCyc:
RXN-9465
|
|
|
|
neryl_diphosphate <=> (-)-limonene + diphosphate
|
4.2.3.104
alpha-humulene synthase
4.2.3.107
(+)-car-3-ene synthase
|
–
–
|
M
|
|
BRENDA:
BS444502
MetaCyc:
RXN-11288
|
|
|
|
(-)-limonene + reduced_flavodoxin + O2 <=> (-)-trans-isopiperitenol + flavin + H2O
|
1.14.14.99
(S)-limonene 3-monooxygenase
|
–
|
K
|
|
BRENDA:
BR36763
KEGG:
R02469
|
|
|
|
(-)-limonene + reduced_flavodoxin + O2 <=> (-)-trans-carveol + flavin + H2O
|
1.14.14.51
(S)-limonene 6-monooxygenase
|
–
|
K
|
|
BRENDA:
BR36764
KEGG:
R02468
|
|
|
|
(-)-limonene + reduced_flavodoxin + O2 <=> (S)-perillyl_alcohol + flavin + H2O
|
1.14.14.52
(S)-limonene 7-monooxygenase
|
–
|
K
|
|
BRENDA:
BR36765
KEGG:
R02470
|
|
|
|
(-)-limonene + NADPH + H+ + O2 <=> (4S)-limonene-1,2-epoxide + NADP+ + H2O
|
1.14.13.107
limonene 1,2-monooxygenase
|
–
|
MK
|
|
KEGG:
R09389
MetaCyc:
RXN-9409
|
|
|
|
(-)-limonene + NADH + H+ + O2 <=> (4S)-limonene-1,2-epoxide + NAD+ + H2O
|
1.14.13.107
limonene 1,2-monooxygenase
|
–
|
K
|
|
KEGG:
R09385
MetaCyc:
RXN-9409_WOP
|
|
|
|
(-)-limonene + reduced_[NADPH-hemoprotein_reductase] + O2 <=> (-)-trans-isopiperitenol + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.99
(S)-limonene 3-monooxygenase
|
–
|
M
|
|
MetaCyc:
--LIMONENE-3-MONOOXYGENASE-RXN
|
|
|
|
(-)-limonene + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (-)-trans-carveol + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.51
(S)-limonene 6-monooxygenase
|
–
|
M
|
|
MetaCyc:
--LIMONENE-6-MONOOXYGENASE-RXN
|
|
|
|
(-)-limonene + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (S)-perillyl_alcohol + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.52
(S)-limonene 7-monooxygenase
|
–
|
M
|
|
MetaCyc:
--LIMONENE-7-MONOOXYGENASE-RXN
|
|
|
|
(-)-limonene + O2 + reduced_ferredoxin_[iron-sulfur]_cluster + H+ <=> (S)-perillyl_alcohol + oxidized_ferredoxin + H2O
|
1.14.15.M10
|
–
|
|
|
MetaCyc:
RXN-20137
|
|
|
|
(-)-limonene + reduced_flavodoxin + O2 <=> (+)-trans-Isopiperitenol + flavin + H2O
|
1.14.14.99
(S)-limonene 3-monooxygenase
|
–
|
|
|
BRENDA:
BS374951
|
|
|
|
(-)-limonene + H2O2 <=> (S)-limonene_cis-1,2-epoxide
|
1.11.2.3
plant seed peroxygenase
|
–
|
|
|
BRENDA:
BS425100
|
|
|
|
(-)-limonene + NADH + H+ + O2 <=> 1,2-epoxymenth-8-ene + NAD+ + H2O
|
1.14.13.107
limonene 1,2-monooxygenase
|
–
|
|
|
BRENDA:
BR49011-a
|
|
|
|
geranyl_diphosphate <=> (-)-limonene
|
4.2.3.15
myrcene synthase
|
–
|
|
|
BRENDA:
BS368435
|
|
|
|
(-)-limonene + NADPH + O2 <=> perillyl_alcohol + NADP+ + H2O
|
1.14.14.52
(S)-limonene 7-monooxygenase
|
–
|
|
|
BRENDA:
BS257986
|
|
|
|
(-)-limonene + NADPH + O2 <=> (-)-trans-carveol + NADP+ + H2O
|
1.14.14.51
(S)-limonene 6-monooxygenase
|
–
|
|
|
BRENDA:
BS257980
|
|
|
|
(-)-limonene + NADPH + O2 <=> (-)-trans-isopiperitenol + NADP+ + H2O
|
1.14.13.47
(S)-limonene 3-monooxygenase
1.14.14.51
(S)-limonene 6-monooxygenase
|
–
–
|
|
|
BRENDA:
BS257984
|
|
|
|
(-)-limonene + NADPH + O2 <=> (S)-perillyl_alcohol + NADP+ + H2O
|
1.14.14.52
(S)-limonene 7-monooxygenase
|
–
|
|
|
BRENDA:
BS374952
|
|
|
|
(-)-limonene + NADPH + O2 <=> (S)-trans-1,2_limonene_epoxide + NADP+ + H2O
|
1.14.14.1
unspecific monooxygenase
|
–
|
|
|
BRENDA:
BS407663
|
|
|
|
(-)-limonene + NADH + H+ + O2 <=> (-)-trans-isopiperitenol + (-)-trans-carveol + (R)-1,2-epoxy-limonene
|
1.14.13.155
alpha-pinene monooxygenase
|
–
|
|
|
BRENDA:
BS442655
|
|
|
|
(-)-limonene + H2O <=> (1S,2S,4R)-limonene-1,2-diol
|
3.3.2.8
limonene-1,2-epoxide hydrolase
|
–
|
|
|
BRENDA:
BS432359
|
|
|
|
(-)-limonene + H2O + ferrocenium_hexafluorophosphate <=> (S)-perillyl_alcohol + reduced_ferrocenium_hexafluorophosphate
|
1.17.99.8
limonene dehydrogenase
|
–
|
|
|
BRENDA:
BS449129
|
|